The missions I've simulated with this program have strong fidelity between the field of view in google earth and in real life. I wonder if your problem might be a difference between the altitude that Litchi thinks you are launching at (the ground) and the actual altitude you're launching at. For example, if you launch from the top of a structure that's well above ground (say 10m), but in mission planning you fixed all your POIs to ground level (i.e. 1m), then your camera angles will be based on the assumption that you're 10m lower than you actually are.
That's one nitpick I have with Litchi and with this simulation program. Whenever I'm launching from an above ground structure I always have to create two versions of the same mission. One, for simulation purposes, in which all the waypoints and POIs are set as if I'm launching from the ground, and the other for actually flying the mission. It's very tedious.